مرکپتوبنزواکسازول بعنوان بازدارنده ی خوردگی مس در محیط کلریدی

: Mercaptobenzimidazole as a copper corrosion inhibitor
 Long-term immersion, 3D-profilometry, and electrochemistry

مرکپتوبنزواکسازول بعنوان بازدارنده ی خوردگی مس در محیط کلریدی: الکتروشیمی، پروفیل سنجی سه بعدی، آنالیز سطحی XPS

ABSTRACT

The high corrosion inhibition effectiveness of 2-mercaptobenzimidazole (MBIH) in 3 wt.% aqueous NaCl solution is reported using long term immersion tests, 3D-profilometry, electrochemical impedance spectroscopy, and potentiodynamic curve measurements. The high corrosion inhibition performance was proven after 180 days of immersion. The impedance spectra were characterized by two time constants relating to charge transfer and finite layer thickness or semi-infinite diffusion of copper ions through the surface layer, therefore Cu corrosion in solution containing MBIH follows kinetic-controlled and diffusion- controlled processes. Moreover, it is shown that MBIH is a mixed-type inhibitor.

 

پوشش های هوشمند خود تمیز شونده جهت حفاظت از اکسیداسیون

Smart self-cleaning coatings for corrosion protection

پوشش های هوشمند خود تمیز شونده جهت حفاظت از اکسیداسیون

ABSTRACT

Self-cleaning surfaces have attracted signifi cant attention in recent years for their potential in both fundamental research and practical applications. Under the scope of self-cleaning smart coatings, this chapter explores the principal features of materials that can be used as protective coatings with an emphasis on the photocatalytic materials that have been developed to date. The chapter also highlights the importance of using titanium dioxide (TiO 2 ) as a semiconductor material in industrial applications since it can act as a photoanode for metal cathodic protection.

چگونه دیرگداز ریختنی مولایتی بسازیم؟!

Let's Make a Mullite Matrix!

چگونه دیرگداز ریختنی مولایتی بسازیم؟!

ABSTRACT

 In the paper "Let's make a castable!"1 we went tbrough proportioning of refractmy castables, and  the beneficial effect microsilica addition has on casting properties. It is however, not only flow and packing that are influenced by microsilica additions, also  high-temperature properties like hot-strength are affected. In the following paper, arguments are  put forward why microsilica additions at relatively high levels bring out the best of the  alumina-silicate castable. Implicitly this also shows why substitution of microsilica by reactive alumina may not be such a good idea after all.

کاربردهای مختلف میکروسیلیس

Silia Fume In Various Applications

کاربردهای مختلف میکروسیلیس

ABSTRACT

Siliea Fume uaagc ia varied and open to 1he imagination of the delligDen. It has become 10 an integralpart oflllllll)' of tho items we use in our daily life. Ill thia section we have chosen  some of tho applicatiau that demoustrate 1ho wrslll:ilily of1ho product. From High Pcrl'OIDilii1Ce  Conaete (HPC) in cODS1ruc:tim projects to:lik in lawn care pruducta ilill Tllther IIIIIUiJg how far  thia "smoke'' by-product bas evolved. Tho earliest applications for hip-slrfilllt!lh aWes. fume conerm. were in columns for Jiish-rise  a1ruc:turea • As CG11Crele stralllh b:mlses coblm size can be nclw.:ed ao4reinforcms steeldeaips in  the columns can be simplified. Smaller cohmms eqaata1 to more ovuaD floor apace available to the  owner of1be structure 1111d a aigail:klllt coat advaotage, particularly in urban aettinaJ.

میکروسیلیس ماده اولیه دیرگداز

MICROSILICA A versatile Refractory Raw Material

میکروسیلیس ماده اولیه دیرگداز؛ کاملاً انعطافپذیر و پرکاربرد

ABSTRACT

An overview is given on the applications of microsilica in refractories starting more than 40 years ago . The role of microsilica in binder systems for briks and castables are discussed including reaction mechanisms at various temperatures . Critical parameters in these reactions are pointed out . Examples of application in castables are presented.

خواص یک نانوکامپوزیت شفاف در برابر مادون قرمز

Properties of an Infrared-Transparent MgO:Y2O3 Nanocomposite

خواص یک نانوکامپوزیت شفاف در برابر مادون قرمز از نوع MgO:Y₂O₃

ABSTRACT

A 50:50 vol% MgO–Y2O3 nanocomposite with ~150 nm grain size was prepared in an attempt to make 3–5 lm infraredtransmitting windows with increased durability and thermal shock resistance. Flexure strength of the composite at 21°C is 679 MPa for 0.88 cm2 under load. Hardness is consistent with that of the constituents with similar grain size. For 3-mm-thick material at 4.85 lm, the total scatter loss is 1.5%, forward scatter is 0.2%, and absorptance is 1.8%. Optical scatter below 2 lm is 100%. Variable intensity OH absorption (~6% absorptance) is observed near 3 lm. The refractive index is ~0.4% below the volume-fraction-weighted average of those of the constituents. Thermal expansion is equal to the volumefraction- weighted average of expansion of the constituents. Specific heat capacity is equal to the mass-fraction-weighted average of heat capacities of the constituents. Thermal conductivity lies between those of the constituents up to 1200 K. Elastic constants lie between those of the constituents. The Hasselman mild thermal shock resistance parameter for the composite is twice as great as that of common 3–5 lm window materials, buthalf as great as that of c-plane sapphire.

مدل سازی تفرق در محیط های کامپوزیتی

Modeling Scatter in Composite Media

مدل سازی تفرق در محیط های کامپوزیتی 

ABSTRACT

A theoretical model of optical scattering in materials consisting of densely packed spherical particles is developed that can be used to predict its optical properties given its physical characteristics. The inputs to this model are the waveband of interest, the complex refractive indices and particle size distribution of the materials that comprise the media (including any contaminants), the density and sizes of any contaminants in the media, and the dimensions of the media slab. The outputs of this model are the specular transmittance and emissivity vs. wavelength of the media, and it’s Bidirectional Scattering Distribution Function (BSDF) vs. scatter angle vs. wavelength. The results of this model are compared to measured transmittance and BSDF data from optical ceramics comprised of densified nanopowders (nanocomposite optical ceramics).

جایگزین های بافت نرم Soft Tissue Replacements

Soft Tissue Replacements

جایگزین های بافت نرم 

ABSTRACT

Blood comes in contact with foreign materials for a short term in extracorporeal devices such as dialyzers , blood oxygenators , ventricular assist devices, and catheters . Long-term vascular implants include heart valve prostheses, vascular grafts , and cardiac pacemakers , among others. In this section, we will be concerned with development of biomaterials for long-term implants, specifically for heart valve prostheses, total artificial heart ( TAH ), and vascular grafts. The primary requirements for biomaterials for long-term implants are biocompatibility, nontoxicity, and durability. Furthermore, the material should be nonirritating to the tissue, resistant to platelet and thrombus deposition, nondegradable in the physiological environment, and neither absorb blood constituents nor release foreign substances into the blood stream [Shim and Lenker, 1988]. In addition, design considerations include that the implant should mimic the function of the organ that it replaces without interfering with the surrounding anatomical structures and must be of suitable size and weight. The biomaterials chosen must be easily available, inexpensive, easily machinable, and sterilizable and have a long storage life.

قابلیت تزریق شدن خمیرهای کلسیم فسفات

Injectability of calcium phosphate pastes

قابلیت تزریق شدن خمیرهای کلسیم فسفات 

ABSTRACT

A theoretical model was developed to assess ways to improve the injectability of calcium phosphate pastes. The theoretical results were then compared to experimental data obtained on calcium phosphate slips. The theoretical approach predicted that the injectability of a cement paste could be improved by an increase of the liquid-to-powder ratio, and a decrease of the particle size and the plastic limit (PL) of the powder. The theoretical results were confirmed by experimental data. Interestingly, an increase of the viscosity of the mixing liquid with small additions of xanthan had a positive effect on the paste injectability. This effect could be due to a change of the PL of the powder or to the lubricating effect of the polymer.

سنتز، شناسایی و خواص نوری نانوذرات اکسید روی

Synthesis, characterization and optical properties of zinc oxide nanoparticles

سنتز، شناسایی و خواص نوری نانوذرات اکسید روی

ABSTRACT

Zinc oxide nanoparticles were synthesized using a simple precipitation method with zinc sulfate and sodium hydroxide as starting materials. The synthesized sample was calcined at different temperatures for 2 h. The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and proton-induced X-ray emission (PIXE) analysis. SEM images show various morphological changes of ZnO obtained by the above method. The average crystallite sizes of the samples were calculated from the full width at half maximum of XRD peaks by using Debye-Scherrer's formula and were found to be in the nanorange. EDS shows that the above route produced highly pure ZnO nanostructures. PIXE technique was used for trace elemental analysis of ZnO. The optical band gaps of various ZnO powders were calculated from UV-visible diffuse reflectance spectroscopic studies.