ABSTRACT
In the paper "Let's make a castable!"1 we went tbrough proportioning of refractmy castables, and the beneficial effect microsilica addition has on casting properties. It is however, not only flow and packing that are influenced by microsilica additions, also high-temperature properties like hot-strength are affected. In the following paper, arguments are put forward why microsilica additions at relatively high levels bring out the best of the alumina-silicate castable. Implicitly this also shows why substitution of microsilica by reactive alumina may not be such a good idea after all.
ABSTRACT
Siliea Fume uaagc ia varied and open to 1he imagination of the delligDen. It has become 10 an integralpart oflllllll)' of tho items we use in our daily life. Ill thia section we have chosen some of tho applicatiau that demoustrate 1ho wrslll:ilily of1ho product. From High Pcrl'OIDilii1Ce Conaete (HPC) in cODS1ruc:tim projects to:lik in lawn care pruducta ilill Tllther IIIIIUiJg how far thia "smoke'' by-product bas evolved. Tho earliest applications for hip-slrfilllt!lh aWes. fume conerm. were in columns for Jiish-rise a1ruc:turea • As CG11Crele stralllh b:mlses coblm size can be nclw.:ed ao4reinforcms steeldeaips in the columns can be simplified. Smaller cohmms eqaata1 to more ovuaD floor apace available to the owner of1be structure 1111d a aigail:klllt coat advaotage, particularly in urban aettinaJ.
ABSTRACT
An overview is given on the applications of microsilica in refractories starting more than 40 years ago . The role of microsilica in binder systems for briks and castables are discussed including reaction mechanisms at various temperatures . Critical parameters in these reactions are pointed out . Examples of application in castables are presented.
ABSTRACT
A 50:50 vol% MgO–Y2O3 nanocomposite with ~150 nm grain size was prepared in an attempt to make 3–5 lm infraredtransmitting windows with increased durability and thermal shock resistance. Flexure strength of the composite at 21°C is 679 MPa for 0.88 cm2 under load. Hardness is consistent with that of the constituents with similar grain size. For 3-mm-thick material at 4.85 lm, the total scatter loss is 1.5%, forward scatter is 0.2%, and absorptance is 1.8%. Optical scatter below 2 lm is 100%. Variable intensity OH absorption (~6% absorptance) is observed near 3 lm. The refractive index is ~0.4% below the volume-fraction-weighted average of those of the constituents. Thermal expansion is equal to the volumefraction- weighted average of expansion of the constituents. Specific heat capacity is equal to the mass-fraction-weighted average of heat capacities of the constituents. Thermal conductivity lies between those of the constituents up to 1200 K. Elastic constants lie between those of the constituents. The Hasselman mild thermal shock resistance parameter for the composite is twice as great as that of common 3–5 lm window materials, buthalf as great as that of c-plane sapphire.
ABSTRACT
A theoretical model of optical scattering in materials consisting of densely packed spherical particles is developed that can be used to predict its optical properties given its physical characteristics. The inputs to this model are the waveband of interest, the complex refractive indices and particle size distribution of the materials that comprise the media (including any contaminants), the density and sizes of any contaminants in the media, and the dimensions of the media slab. The outputs of this model are the specular transmittance and emissivity vs. wavelength of the media, and it’s Bidirectional Scattering Distribution Function (BSDF) vs. scatter angle vs. wavelength. The results of this model are compared to measured transmittance and BSDF data from optical ceramics comprised of densified nanopowders (nanocomposite optical ceramics).
ABSTRACT
Blood comes in contact with foreign materials for a short term in extracorporeal devices such as dialyzers , blood oxygenators , ventricular assist devices, and catheters . Long-term vascular implants include heart valve prostheses, vascular grafts , and cardiac pacemakers , among others. In this section, we will be concerned with development of biomaterials for long-term implants, specifically for heart valve prostheses, total artificial heart ( TAH ), and vascular grafts. The primary requirements for biomaterials for long-term implants are biocompatibility, nontoxicity, and durability. Furthermore, the material should be nonirritating to the tissue, resistant to platelet and thrombus deposition, nondegradable in the physiological environment, and neither absorb blood constituents nor release foreign substances into the blood stream [Shim and Lenker, 1988]. In addition, design considerations include that the implant should mimic the function of the organ that it replaces without interfering with the surrounding anatomical structures and must be of suitable size and weight. The biomaterials chosen must be easily available, inexpensive, easily machinable, and sterilizable and have a long storage life.
ABSTRACT
A theoretical model was developed to assess ways to improve the injectability of calcium phosphate pastes. The theoretical results were then compared to experimental data obtained on calcium phosphate slips. The theoretical approach predicted that the injectability of a cement paste could be improved by an increase of the liquid-to-powder ratio, and a decrease of the particle size and the plastic limit (PL) of the powder. The theoretical results were confirmed by experimental data. Interestingly, an increase of the viscosity of the mixing liquid with small additions of xanthan had a positive effect on the paste injectability. This effect could be due to a change of the PL of the powder or to the lubricating effect of the polymer.
ABSTRACT
Zinc oxide nanoparticles were synthesized using a simple precipitation method with zinc sulfate and sodium hydroxide as starting materials. The synthesized sample was calcined at different temperatures for 2 h. The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and proton-induced X-ray emission (PIXE) analysis. SEM images show various morphological changes of ZnO obtained by the above method. The average crystallite sizes of the samples were calculated from the full width at half maximum of XRD peaks by using Debye-Scherrer's formula and were found to be in the nanorange. EDS shows that the above route produced highly pure ZnO nanostructures. PIXE technique was used for trace elemental analysis of ZnO. The optical band gaps of various ZnO powders were calculated from UV-visible diffuse reflectance spectroscopic studies.
ABSTRACT
The structural properties of Mg2 + and Al3 + co-substituted Li0.5Fe2.5O4 are studied by synthesizing the spinel solid solution series MgxAl2xLi0.5(1 x)Fe2.5(1 x)O4. Polycrystalline samples of this series with x = 0.0, 0.1, 0.2, 0.3, 0.4 and 0.5 have been prepared by double-sintering ceramic method. The structural details like: lattice constant and distribution of cations in the tetrahedral and octahedral interstitial voids have been deduced through X-ray diffraction (XRD) data analysis. The x dependence of bond length, oxygen positional parameter, site ionic radii, bulk density, porosity and shrinkages have also been determined.
آلیاژ منیزیم ، آلومینیوم، روی
آلیاژ منیزیم، زیر کونیوم
آلیاژ منیزیم، کروم
AZ91C ،AZ92A،EQ21A،EZ33A،HK31A،HZ32A،AZ91A،AZ91B،AZ91D،AZ91E،AZ81A
ABSTRACT
The principles which govern heat treatment of metals and alloys are applicable to both ferrous and nonferrous alloys. However, in practice there are sufficient differences to make it convenient to emphasize as separate topics the peculiarities of the alloys of each class in their response to heat treatment. For example, in nonferrous alloys, eutectoid transformations, which play such a prominent role in steels, are seldom encountered, so there is less concern with principles associated with time-temperaturetransformation diagrams and with martensite formation. On the other hand, the principles associated with chemical homogenization of cast structures are applicable to many alloys in both classes. Diffusion Process The diffusion process is involved in nearly all heat treatments for nonferrous alloys. Common treatments include:
• Annealing after cold working
• Homogenization of castings
• Precipitation hardening treatments
• Development of two-phase structures